I'm someone who learned to code via years of use of Dreamweaver and I must say I'm still partial to the program (especially the Macromedia help and forums area if I'm stuck!). I also think it would be tough to learn PS if you've first been using Fireworks. PS was originally developed to do a whole lot more things than most graphic designers today need to know or would use. I still like putting alien heads on babies, like the tabloids do, though, just for a laugh now and then
My personal dislike is MS Word's way of converting a file into HTML ever since Windows 98. Talk about a coding nightmare! Microsoft inserts all this crap code in your documents, which don't usually screw things up, but are totally unnecessary. This really is building a whole bunch of website builders who don't look at the underlying code at all and a bunch of pages with bloated code that slows everything down. Microsoft isn't the only ones who do this of course - any WSIWYG is going to do a similar thing, but I really miss earlier versions of Word, where you could take a Word document, change it to HTML and you'd get a great page with little extra coding. Ah, those were the days! Notepad does indeed still rule!